Which is a wrong statement?

  • A
    In $\ln k$ vs $\frac{1}{T}$ plot is a straight line
  • B
    Presence of catalyst will not alter the value of $E_a$
  • C
    Rate constant $k = $ Arrhenius constant $A$: if $E_a = 0$
  • D
    $e^{-E_a / RT}$ gives the fraction of reactant molecules that are activated at the given temp

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The time required for $10 \%$ completion of a first order reaction at $298 \,K$ is equal to that required for its $25 \%$ completion at $308 \,K$. If the value of $A$ is $4 \times 10^{10} \,s^{-1}$,calculate $k$ at $318 \,K$ and $E_a$.

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Explain: How is the value of activation energy determined based on the Arrhenius equation?

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The temperature dependence of the rate constant $k$ is expressed as $k = A e^{-E_a / RT}$. When a plot between $\log k$ and $1/T$ is plotted,we get the graph as shown. What is the value of the slope in the graph?

For an endothermic reaction,the energy of activation is $E_a$ and the enthalpy of reaction is $\Delta H$ (both in $kJ/mol$). The minimum value of $E_a$ will be:

For a reaction $A \rightarrow B$,the enthalpy of reaction is $-4.2 \ kJ \ mol^{-1}$ and the enthalpy of activation is $9.6 \ kJ \ mol^{-1}$. The correct potential energy profile for the reaction is shown in which option?

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