Which of the following aqueous molal solutions has the highest freezing point?

$31 \ g$ of ethylene glycol $(C_2H_6O_2)$ is dissolved in $600 \ g$ of water. The freezing point depression of the solution is ($K_f$ for water is $1.86 \ K \ kg \ mol^{-1}$) (in $K$)

The freezing point of a $0.05 \ molal$ solution of a non-electrolyte in water is $(K_f = 1.86 \ K \ kg \ mol^{-1})$:

The freezing point of a $5\%$ (by mass) aqueous solution of sucrose is $271 \, K$ and the freezing point of pure water is $273.15 \, K$. The freezing point of a $5\%$ (by mass) aqueous solution of glucose is .......... $K$.

The aqueous solution of urea has a freezing point of $-0.6\,^\circ C$. To prepare such a solution,how many grams of urea are needed to dissolve in $3\,kg$ of water? $(M = 60\,g\,mol^{-1}, K_{f} = 1.5\,^\circ C\,kg\,mol^{-1})$

Given that $\Delta T_f$ is the depression in freezing point of the solvent in a solution of a non-volatile solute of molality $m$,the quantity $\lim_{m \to 0} \left( \frac{\Delta T_f}{m} \right)$ is equal to: