Which one of the following is not formed when a mixture of methyl bromide and bromobenzene is heated with sodium metal in the presence of dry ether?

  • A
    Diphenyl
  • B
    Propane
  • C
    Toluene
  • D
    Ethane

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Identify the product in the following reaction:

Consider the following statements:
$(1)$ Bridgehead halides are inert towards both $S_{N^1}$ and $S_{N^2}$ reactions (until one of the ring size is an eight-membered ring).
$(2)$ The first step in both $S_{N^1}$ and $E_1$ reactions is the same.
$(3)$ $S_{N^2}$ reactions proceed with total retention of configuration.
$(4)$ $E_2$ eliminations are favored by the use of a solvent of low polarity and a high concentration of a strong base.
Which of the above statements are correct?

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Identify the products formed and comment on the optical activity of the products for the following reaction: $3$-phenylcyclopent-$2$-en-$1$-one + $H_2$ $(2-3 \ atm)$ $\xrightarrow{10\% Pd/C, \text{Ethanol}}$ ?

Explain two differences between haloalkanes and haloarenes.

Match the reactants in Column-$(I)$ with the products formed in Column-$(II)$.
Column-$(I)$ (Reactants)Column-$(II)$ (Major Products)
$(A)$ $C_6H_5CH_3 + X_2 \xrightarrow{Fe, \text{dark}}$$(i)$ $C_6H_5CH(Br)CH_3$
$(B)$ $C_6H_5NH_2 \xrightarrow{NaNO_2, HX, 273-278 \ K}$$(ii)$ $C_6H_5N_2^+X^-$
$(C)$ $C_6H_5N_2^+X^- \xrightarrow{Cu_2X_2}$$(iii)$ $p-X-C_6H_4CH_3 + o-X-C_6H_4CH_3$
$(D)$ $C_6H_5CH_2CH_3 \xrightarrow{Br_2, \Delta \text{ or } UV \text{ light}}$$(iv)$ $C_6H_5X$

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