$[Fe(H_2O)_6]^{3+}$ is strongly paramagnetic whereas $[Fe(CN)_6]^{3-}$ is weakly paramagnetic. Explain.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) In both $[Fe(H_2O)_6]^{3+}$ and $[Fe(CN)_6]^{3-}$,$Fe$ exists in the $+3$ oxidation state,i.e.,in $d^5$ configuration.
Since $CN^{-}$ is a strong field ligand,it causes the pairing of unpaired electrons. Therefore,there is only one unpaired electron left in the $d$-orbital.
Therefore,
$\mu = \sqrt{n(n+2)}$
$= \sqrt{1(1+2)}$
$= \sqrt{3}$
$= 1.732 \, BM$
On the other hand,$H_2O$ is a weak field ligand. Therefore,it cannot cause the pairing of electrons. This means that the number of unpaired electrons is $5$.
Therefore,
$\mu = \sqrt{n(n+2)}$
$= \sqrt{5(5+2)}$
$= \sqrt{35}$
$\simeq 5.92 \, BM$
Thus,it is evident that $[Fe(H_2O)_6]^{3+}$ is strongly paramagnetic (with $5$ unpaired electrons),while $[Fe(CN)_6]^{3-}$ is weakly paramagnetic (with $1$ unpaired electron).

Explore More

Similar Questions

If the crystal field splitting energy of a tetrahedral complex $\Delta_t$ of the type $[ML_4]^{n+}$ is $x \ eV$,what is the crystal field splitting energy with respect to an octahedral complex,$[ML_6]^{n+}$?

Match List-$I$ with List-$II$.
List-$I$ (Coordination entity) List-$II$ (Wavelength of light absorbed in $nm$)
$A$. $[CoCl(NH_3)_5]^{2+}$ $I$. $310$
$B$. $[Co(NH_3)_6]^{3+}$ $II$. $475$
$C$. $[Co(CN)_6]^{3-}$ $III$. $535$
$D$. $[Cu(H_2O)_4]^{2+}$ $IV$. $600$

Choose the correct answer from the options given below:

In which case is a $d^7$ complex species more stable?

Which of the following complexes has the maximum number of unpaired electrons in the $e_g$ set of orbitals?

Complexes containing halide ligands are generally .....

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo