$A$ given nitrogen-containing aromatic compound $A$ reacts with $Sn/HCl,$ followed by $HNO_2$ to give an unstable compound $B$. $B,$ on treatment with phenol,forms a beautiful coloured compound $C$ with the molecular formula $C_{12}H_{10}N_2O.$ The structure of compound $A$ is

  • A
    Aniline
  • B
    Nitrobenzene
  • C
    Benzonitrile
  • D
    Benzamide

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In which of the following reactions is a tertiary amine formed?

Match List-$I$ with List-$II$ and select the correct answer.
List-$I$ List-$II$
$1.$ Aniline $a.$ Used in the preparation of azo dyes
$2.$ Nitrobenzene $b.$ Sulpha drug
$3.$ Sulphanilamide $c.$ Solvent in Friedel-Crafts reaction
$4.$ Trinitrotoluene $d.$ Used as an explosive

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You have been given four bottles marked $A, B, C$ and $D$ each containing one of the organic compounds given below:
$I: C_6H_5CH_2NH_2$$II: C_6H_5CH_2COOH$
$III: C_6H_5CH_2CH_3$$IV: C_6H_5CH_2CH(NH_2)COOH$

The following observations were made:
$(i)$ The compound in bottle $A$ did not dissolve in either $1 \ N \ NaOH$ or $1 \ N \ HCl$.
$(ii)$ The compound in bottle $B$ dissolved in $1 \ N \ NaOH$ but not in $1 \ N \ HCl$.
$(iii)$ The compound in bottle $C$ dissolved in both $1 \ N \ NaOH$ and $1 \ N \ HCl$.
$(iv)$ The compound in bottle $D$ did not dissolve in $1 \ N \ NaOH$ but dissolved in $1 \ N \ HCl$.
$(a)$ Indicate the compounds in: bottle $A = \dots$,bottle $B = \dots$,bottle $C = \dots$ and bottle $D = \dots$.
$(b)$ The compound with the highest solubility in distilled water is .......

Which among the following represents reagent $A$ in the given reaction?
$C_6H_5N_2^+Cl^- + A \xrightarrow{NaOH} \text{Product (Orange-red dye)}$

In the reaction sequence $CH_3CH_2Br$ $\xrightarrow{AgCN} A$ $\xrightarrow{H_3O^+} HCOOH + B; B$ $\xrightarrow{CHCl_3/KOH} A$ $\xrightarrow{Reduction} C$,what are $A, B,$ and $C$ respectively?

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