The rate of a gaseous reaction is given by the expression $k[A][B]^{2}$. If the volume of the vessel is reduced to one-half of the initial volume,the reaction rate as compared to the original rate is:

  • A
    $1/16$
  • B
    $1/8$
  • C
    $8$
  • D
    $16$

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The reaction $3ClO^{-} \rightarrow ClO_{3}^{-} + 2Cl^{-}$ occurs in the following two steps:
$(i)$ $ClO^{-} + ClO^{-} \xrightarrow{K_{1}} ClO_{2}^{-} + Cl^{-}$ (Slow step)
$(ii)$ $ClO_{2}^{-} + ClO^{-} \xrightarrow{K_{2}} ClO_{3}^{-} + Cl^{-}$ (Fast step)
Then the rate of the given reaction is equal to . . . . . . .

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The following reactions occur for the reaction of $NO$ with $Br_2$ to form $NOBr$:
$NO_{(g)} + Br_{2_{(g)}} \rightleftharpoons NOBr_{2_{(g)}}$
$NOBr_{2_{(g)}} + NO_{(g)} \rightarrow 2 NOBr_{(g)}$
If the second reaction is the rate-determining step,the order of the reaction with respect to $NO_{(g)}$ will be:

For a given reaction $t_{1/2} = \frac{1}{k \cdot a}$,the order of reaction will be:

The rate constant of the reaction,$2 H_2O_2 \rightarrow 2 H_2O + O_2$ is $3 \times 10^{-3} \ min^{-1}$. At what concentration of $H_2O_2$ will the rate of reaction be $2 \times 10^{-4} \ M \ s^{-1}$?

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